Bellamy and Cadogan say that a(4) = 2*3^86093441, which is too large to include here.
Bellamy, O. S.; Cadogan, C. C. Subsets of positive integers: their cardinality and maximality properties. Proceedings of the Tenth Southeastern Conference on Combinatorics, Graph Theory and Computing (Florida Atlantic Univ., Boca Raton, Fla., 1979), pp. 167--178, Congress. Numer., XXIII-XXIV, Utilitas Math., Winnipeg, Man., 1979. MR0561043 (82b:10006)