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A000623 Number of monosubstituted alkanes C(n)H(2n+1)-X of the form shown in the Comments lines that are stereoisomers.
(Formerly M4125 N1712)
8

%I M4125 N1712 #21 Feb 01 2022 01:05:40

%S 0,0,0,0,0,0,6,18,66,208,646,1962,5962,18014,54578,165650,504220,

%T 1539330,4713742,14475936,44578668,137634872,425970290,1321323952,

%U 4107268140,12792332438,39915708564,124762612530,390593588402,1224681912368,3845387953884,12090382743374

%N Number of monosubstituted alkanes C(n)H(2n+1)-X of the form shown in the Comments lines that are stereoisomers.

%C ....X

%C ....|

%C R-C-R' (tertiary)

%C ....|

%C ....R"

%C Let the entries in the nine columns of Blair and Henze's Table I (JACS 54 (1932), p. 1098) be denoted by Ps(n), Pn(n), Ss(n), Sn(n), Ts(n), Tn(n), As(n), An(n), T(n) respectively (here P = Primary, S = Secondary, T = Tertiary, s = stereoisomers, n = non-stereoisomers and the last column T(n) gives total).

%C Then Ps (and As) = A000620, Pn (and An, Sn) = A000621, Ss = A000622, Ts = this sequence, Tn = A000624, T = A000625. Recurrences generating these sequences are given in the Maple program in A000620.

%D N. J. A. Sloane, A Handbook of Integer Sequences, Academic Press, 1973 (includes this sequence).

%D N. J. A. Sloane and Simon Plouffe, The Encyclopedia of Integer Sequences, Academic Press, 1995 (includes this sequence).

%H Vaclav Kotesovec, <a href="/A000623/b000623.txt">Table of n, a(n) for n = 1..1930</a>

%H C. M. Blair and H. R. Henze, <a href="http://dx.doi.org/10.1021/ja01342a036">The number of stereoisomeric and non-stereoisomeric mono-substitution products of the paraffins</a>, J. Amer. Chem. Soc., 54 (3) (1932), 1098-1106.

%H C. M. Blair and H. R. Henze, <a href="/A000620/a000620.pdf">The number of stereoisomeric and non-stereoisomeric mono-substitution products of the paraffins</a>, J. Amer. Chem. Soc., 54 (3) (1932), 1098-1105. (Annotated scanned copy)

%F a(n) ~ c * b^n / n^(3/2), where b = 3.287112055584474991259... (see A239803), c = 0.069641252627300354415... (see A239808). - _Vaclav Kotesovec_, Mar 27 2014

%Y Cf. A000620-A000625, A239803, A239808.

%K nonn

%O 1,7

%A _N. J. A. Sloane_

%E Additional comments from Bruce Corrigan, Nov 04 2002

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